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| Men's doubles | |
|---|---|
| 2014 Italian Open | |
| Champions | |
| Runners-up | |
| Score | 6–4, 7–6(7–2) |
Bob Bryan and Mike Bryan were the defending champions, but lost to Daniel Nestor and Nenad Zimonjić in the semifinals.
Nestor and Zimonjić went on to win the title, defeating Robin Haase and Feliciano López in the final, 6–4, 7–6(7–2).
Seeds
All seeds receive a bye into the second round.
Bob Bryan / Mike Bryan (semifinals)
Alexander Peya / 
Bruno Soares (second round)
Ivan Dodig / Marcelo Melo (quarterfinals)
David Marrero / Fernando Verdasco (quarterfinals)
Nicolas Mahut / Édouard Roger-Vasselin (second round)
Daniel Nestor / 
Nenad Zimonjić (champions)
Łukasz Kubot / 
Robert Lindstedt (second round)
Treat Huey / 
Dominic Inglot (second round)
Draw
Key
- Q = Qualifier
- WC = Wild card
- LL = Lucky loser
- Alt = Alternate
- SE = Special exempt
- PR = Protected ranking
- ITF = ITF entry
- JE = Junior exempt
- w/o = Walkover
- r = Retired
- d = Defaulted
- SR = Special ranking
Finals
| Semifinals | Final | ||||||||||||
| 1 |  Bob Bryan Mike Bryan
| 63 | 6 | ||||||||||
| 6 |  Daniel Nestor  Nenad Zimonjić
| 77 | 4 | ||||||||||
| 6 | Daniel Nestor Nenad Zimonjić
| 6 | 77 | ||||||||||
 Robin Haase  Feliciano López
| 4 | 62 | |||||||||||
| Robin Haase Feliciano López
| 6 | 6 | |||||||||||
 Grigor Dimitrov  Lukáš Rosol
| 2 | 4 | |||||||||||
Top half
| First round | Second round | Quarterfinals | Semifinals | ||||||||||||||||||||||||
| 1 | B Bryan M Bryan
| 7 | 6 | ||||||||||||||||||||||||
J-J Rojer  H Tecău
| 6 | 3 |  R Bopanna  A-u-H Qureshi
| 5 | 1 | ||||||||||||||||||||||
| R Bopanna A-u-H Qureshi
| 3 | 6 | 1 | B Bryan M Bryan
| w/o | ||||||||||||||||||||||
 T Haas R Štěpánek
| 3 | 6 | T Haas R Štěpánek
| ||||||||||||||||||||||||
| J Isner S Lipsky
| 6 | 2 | T Haas R Štěpánek
| 6 | 61 | ||||||||||||||||||||||
| 7 |  Ł Kubot  R Lindstedt
| 2 | 77 | ||||||||||||||||||||||||
| 1 | B Bryan M Bryan
| 63 | 6 | ||||||||||||||||||||||||
| 6 | D Nestor N Zimonjić
| 77 | 4 | ||||||||||||||||||||||||
| 4 | D Marrero F Verdasco
| 7 | 6 | ||||||||||||||||||||||||
| M Fyrstenberg M Matkowski
| 3 | 6 | P Andújar M Granollers
| 5 | 1 | ||||||||||||||||||||||
| P Andújar M Granollers
| 6 | 4 | 4 | D Marrero F Verdasco
| 6 | 3 | |||||||||||||||||||||
| WC |  M Cecchinato A Seppi
| 66 | 2 | 6 | D Nestor N Zimonjić
| 4 | 6 | ||||||||||||||||||||
| PR |  K Anderson  J Melzer
| 78 | 6 | PR | K Anderson J Melzer
| 6 | 64 | ||||||||||||||||||||
| 6 | D Nestor N Zimonjić
| 3 | 77 | ||||||||||||||||||||||||
Bottom half
| First round | Second round | Quarterfinals | Semifinals | ||||||||||||||||||||||||
| 8 |  T Huey  D Inglot
| 62 | 2 | ||||||||||||||||||||||||
| PR | S Bolelli F Fognini
| 3 | 2 | R Haase F López
| 77 | 6 | |||||||||||||||||||||
| R Haase F López
| 6 | 6 | R Haase F López
| 6 | 6 | ||||||||||||||||||||||
 M Mirnyi  M Youzhny
| 6 | 5 | 3 |  I Dodig  M Melo
| 3 | 2 | |||||||||||||||||||||
| WC | D Bracciali P Starace
| 3 | 7 | M Mirnyi M Youzhny
| 65 | 7 | |||||||||||||||||||||
| 3 | I Dodig M Melo
| 77 | 5 | ||||||||||||||||||||||||
| R Haase F López
| 6 | 6 | |||||||||||||||||||||||||
| G Dimitrov L Rosol
| 2 | 4 | |||||||||||||||||||||||||
| 5 |  N Mahut É Roger-Vasselin
| 4 | 77 | ||||||||||||||||||||||||
| V Pospisil D Tursunov
| 4 | 77 | M Čilić  S González
| 6 | 62 | ||||||||||||||||||||||
| M Čilić S González
| 6 | 63 | M Čilić S González
| 6 | 4 | ||||||||||||||||||||||
| G Dimitrov L Rosol
| 77 | 77 | G Dimitrov L Rosol
| 4 | 6 | ||||||||||||||||||||||
 J S Cabal R Farah
| 65 | 65 | G Dimitrov L Rosol
| 6 | 3 | ||||||||||||||||||||||
| 2 | A Peya B Soares
| 4 | 6 | ||||||||||||||||||||||||